Cu(II) Complexes of a Tripodal Tetraamine Incorporating a Pendant Arm and Related Schiff Base Ligand; X-ray Crystal Structure and Spectral Studies

Document Type : Research Paper

Authors

1 Chemistry Department, Payame Noor University, 19395-4697 Tehran, Iran

2 Physics Department, Payame Noor University, 19395-4697 Tehran, Iran

3 Chemistry Department, Tuyserkan Branch, Islamic Azad University, Tuyserkan, Iran

4 Agricultural Science Department,Payame Noor University, 19395-4697, Tehran, Iran

Abstract

Two new Cu(II) complexes, [Cu(L22py)Cl]ClO4 (1), Cu(L22pysa) (2), {L22py = N-(2-pyridylmethyl)-N-(2-aminoethyl)-1,2-diaminoethane, were prepared through the reaction of suitable metal ion salts, L22py, and salicylaldehyde in the presence of NaClO4. The ligands were characterized by elemental analysis, IR spectroscopy, and 13C and 1H NMR analysis. Additionally, X-ray crystal structure analysis was performed for complex 1. The X-ray study revealed that the Cu(II) ion exhibits a square configuration.

Graphical Abstract

Cu(II) Complexes of a Tripodal Tetraamine Incorporating a Pendant Arm and Related Schiff Base Ligand; X-ray Crystal Structure and Spectral Studies

Keywords

Inorganic Chemistry Research
Volume 7, Issue 1
July 2023
Pages 22-26

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History

  • Receive Date: 23 September 2023
  • Revise Date: 18 October 2023
  • Accept Date: 18 October 2023

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