Dehghani-Firouzabadi, A., Alizadeh, T. (2016). Synthesis and Characterization of Binuclear Zn(II) Complex of N2O2S Symmetrical Potentially Pentadentate Schiff Base Ligand. Inorganic Chemistry Research, 1(2), 115-122. doi: 10.22036/icr.2017.43519.1028
Ahmad Ali Dehghani-Firouzabadi; Tahereh Alizadeh. "Synthesis and Characterization of Binuclear Zn(II) Complex of N2O2S Symmetrical Potentially Pentadentate Schiff Base Ligand". Inorganic Chemistry Research, 1, 2, 2016, 115-122. doi: 10.22036/icr.2017.43519.1028
Dehghani-Firouzabadi, A., Alizadeh, T. (2016). 'Synthesis and Characterization of Binuclear Zn(II) Complex of N2O2S Symmetrical Potentially Pentadentate Schiff Base Ligand', Inorganic Chemistry Research, 1(2), pp. 115-122. doi: 10.22036/icr.2017.43519.1028
Dehghani-Firouzabadi, A., Alizadeh, T. Synthesis and Characterization of Binuclear Zn(II) Complex of N2O2S Symmetrical Potentially Pentadentate Schiff Base Ligand. Inorganic Chemistry Research, 2016; 1(2): 115-122. doi: 10.22036/icr.2017.43519.1028
Synthesis and Characterization of Binuclear Zn(II) Complex of N2O2S Symmetrical Potentially Pentadentate Schiff Base Ligand
Department of Chemistry, Faculty of Science, Yazd University, 89195-741 Yazd, Iran
Abstract
The reactions of 1 - chloro - 2 - nitro benzene with 2 - Amino thio phenol yield the 2 - ( ( nitro phenyl ) thio ) aniline and then 2 , 2' - thio dianiline of this compound was prepared . Also the symmetrical potentially pentadentate N 2 O 2 S Schiff base ligand 2 , 2' - ( ( ( thio bis (1 , 2 - phenylene ) ) bis ( azanilidene ) ) bis ( methenilidene ) ) diphenol ( H 2 L ) obtain by added salicylaldehyde . These compound have been characterized by FT - IR , 1 H NMR and Mass Spectrometry . Bi - nuclear Zn ( II ) complex of this ligand was prepared and structurally characterized by X - ray crystallography . The coordination geometry around Zn ( II ) is intermediate between trigonal bipyramidal and square pyramidal , τ = 0.54.
